Trimethylenemethane cycloaddition

http://dbpedia.org/resource/Trimethylenemethane_cycloaddition an entity of type: WikicatOrganicReactions

Trimethylenemethane cycloaddition is the formal [3+2] annulation of trimethylenemethane (TMM) derivatives to two-atom pi systems. Although TMM itself is too reactive and unstable to be stored, reagents which can generate TMM or TMM synthons in situ can be used to effect cycloaddition reactions with appropriate electron acceptors. Generally, electron-deficient pi bonds undergo cyclization with TMMs more easily than electron-rich pi bonds. rdf:langString
rdf:langString Trimethylenemethane cycloaddition
xsd:integer 27568805
xsd:integer 1066326253
rdf:langString Trimethylenemethane cycloaddition is the formal [3+2] annulation of trimethylenemethane (TMM) derivatives to two-atom pi systems. Although TMM itself is too reactive and unstable to be stored, reagents which can generate TMM or TMM synthons in situ can be used to effect cycloaddition reactions with appropriate electron acceptors. Generally, electron-deficient pi bonds undergo cyclization with TMMs more easily than electron-rich pi bonds.
xsd:nonNegativeInteger 11922

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