Thallane
http://dbpedia.org/resource/Thallane an entity of type: Thing
氢化铊（系统名三氢化铊）是一种无机化合物，实验式为TlH3。它还没有批量获得，因此其批量性质仍然未知。但氢化铊分子已从固体气体中分离出来。氢化铊主要用于学术用途。 氢化铊是最简单的铊氢化物。铊是13族金属中最重的一种;13族氢化物的稳定性随周期数的增加而降低。这通常是由于金属价层轨道与氢原子的1s轨道重叠不佳造成的。尽管早期的报告令人鼓舞，但不太可能分离出一种铊氢化物。氢化铊仅在基体分离研究中被观察到；红外光谱是在氢气存在的情况下，用激光烧蚀铊，在气相中得到的。本研究证实了Schwerdtfeger第一原理计算的某些方面，该第一原理计算表明铊和铟氢化物具有相似的稳定性。迄今为止，还没有确认分离铊氢化物络合物。
rdf:langString
Thallane (systematically named trihydridothallium) is an inorganic compound with the empirical chemical formula TlH3. It has not yet been obtained in bulk, hence its bulk properties remain unknown. However, molecular thallane has been isolated in solid gas matrices. Thallane is mainly produced for academic purposes.
rdf:langString
rdf:langString
Thallane
rdf:langString
氢化铊
rdf:langString
Thallane
rdf:langString
Thallane
xsd:integer
31387138
xsd:integer
1062742116
rdf:langString
Thallane-3D-vdW.png
rdf:langString
Thallane-3D-sticks.png
rdf:langString
Thallane
rdf:langString
Thallium hydride
rdf:langString
Thallium trihydride
rdf:langString
Hydrogen thallide
rdf:langString
Thallane
rdf:langString
Trihydridothallium
rdf:langString
Thallane (systematically named trihydridothallium) is an inorganic compound with the empirical chemical formula TlH3. It has not yet been obtained in bulk, hence its bulk properties remain unknown. However, molecular thallane has been isolated in solid gas matrices. Thallane is mainly produced for academic purposes. It is the simplest thallanes. Thallium is the heaviest member of the Group 13 metals; the stability of group 13 hydrides decreases with increasing periodic number. This is commonly attributed to poor overlap of the metal valence orbitals with that of the 1s orbital of Hydrogen. Despite encouraging early reports, it is unlikely that a thallane species has been isolated. Thallanes have been observed only in matrix isolation studies; the infrared spectrum was obtained in the gas phase by laser ablation of thallium in the presence of hydrogen gas. This study confirmed aspects of ab initio calculations conducted by Schwerdtfeger which indicated the similar stability of thallium and indiganes. There has not been a confirmed isolation of a thallium hydride complex to date.
rdf:langString
氢化铊（系统名三氢化铊）是一种无机化合物，实验式为TlH3。它还没有批量获得，因此其批量性质仍然未知。但氢化铊分子已从固体气体中分离出来。氢化铊主要用于学术用途。 氢化铊是最简单的铊氢化物。铊是13族金属中最重的一种;13族氢化物的稳定性随周期数的增加而降低。这通常是由于金属价层轨道与氢原子的1s轨道重叠不佳造成的。尽管早期的报告令人鼓舞，但不太可能分离出一种铊氢化物。氢化铊仅在基体分离研究中被观察到；红外光谱是在氢气存在的情况下，用激光烧蚀铊，在气相中得到的。本研究证实了Schwerdtfeger第一原理计算的某些方面，该第一原理计算表明铊和铟氢化物具有相似的稳定性。迄今为止，还没有确认分离铊氢化物络合物。
xsd:nonNegativeInteger
3533
rdf:langString
Thallium hydride
rdf:langString
Thallium trihydride
rdf:langString
Hydrogen thallide
rdf:langString
Thallane
rdf:langString
Thallane (substitutive)
rdf:langString
Trihydridothallium (additive)