Sulfur trioxide pyridine complex
http://dbpedia.org/resource/Sulfur_trioxide_pyridine_complex an entity of type: Thing
三氧化硫吡啶是一种有机化合物,化学式为C5H5NSO3。它是无色固体,可溶于极性有机溶剂。它是路易斯碱吡啶和路易斯酸三氧化硫的加合物。它主要用于提供三氧化硫,如由醇类制备硫酸酯: ROH + C5H5NSO3 → [C5H5NH]+[ROSO3]− 这个试剂可用于很多磺酰化反应,如呋喃的磺酰化反应。它在Parikh–Doering氧化反应中作为亲电试剂。
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Sulfur trioxide pyridine complex is the compound with the formula C5H5NSO3. It is a colourless solid that dissolves in polar organic solvents. It is the adduct formed from the Lewis base pyridine and the Lewis acid sulfur trioxide. The compound is mainly used as a source of sulfur trioxide, for example in the synthesis of sulfate esters from alcohols: ROH + C5H5NSO3 → [C5H5NH]+[ROSO3]− It also is useful for sulfamations: R2NH + C5H5NSO3 → C5H5N + R2NSO3H
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Sulfur trioxide pyridine complex
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三氧化硫吡啶
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5578011
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1118574862
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Sulfur-trioxide-pyridine-complex-2D-skeletal.png
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Sulfur-trioxide-pyridine-complex-3D-vdW.png
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450637936
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Sulfur trioxide pyridine complex is the compound with the formula C5H5NSO3. It is a colourless solid that dissolves in polar organic solvents. It is the adduct formed from the Lewis base pyridine and the Lewis acid sulfur trioxide. The compound is mainly used as a source of sulfur trioxide, for example in the synthesis of sulfate esters from alcohols: ROH + C5H5NSO3 → [C5H5NH]+[ROSO3]− It also is useful for sulfamations: R2NH + C5H5NSO3 → C5H5N + R2NSO3H The compound is used for sulfonylation reactions, especially in the sulfonylation of furans. It is also an activating electrophile in a Parikh-Doering oxidation.
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三氧化硫吡啶是一种有机化合物,化学式为C5H5NSO3。它是无色固体,可溶于极性有机溶剂。它是路易斯碱吡啶和路易斯酸三氧化硫的加合物。它主要用于提供三氧化硫,如由醇类制备硫酸酯: ROH + C5H5NSO3 → [C5H5NH]+[ROSO3]− 这个试剂可用于很多磺酰化反应,如呋喃的磺酰化反应。它在Parikh–Doering氧化反应中作为亲电试剂。
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2998