Manganese(III) chloride

rdf:langString Manganese(III) chloride

rdf:langString manganese(III) chloride, bis(triphenylphopshine oxide)

rdf:langString manganese chloride, bis

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rdf:langString Trichloridobistriphenylphosphineoxidemanganese.jpg

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rdf:langString Manganese trichloride

rdf:langString trichloridobismanganese

rdf:langString Manganese(III) chloride (Mn(III)Cl3) is not a stable compound and has only been isolated under specialized circumstances. The simple salt, Mn(III)Cl3, is reported to be a dark solid that decomposes above -40 °C. This is in contrast to its neighbors iron(III) chloride, chromium(III) chloride, technetium(III) chloride, and rhenium(III) chloride trimer, which are all isolable compounds and used in chemical synthesis. Ethereal adducts of Mn(III)Cl3 have been isolated, but these are thermally unstable and rapidly decompose at room temperature in the solid or solution state. Meta stable acetonitrile solvated Mn(III)Cl3 can be prepared at room temperature by treating [Mn12O12(OAc)16(H2O)4] with trimethylsilylchloride. Similarly, treatment of permanganate salts with trimethylsilylchloride generates solutions containing Mn(III)–Cl species for alkene dichlorination reactions; electrocatalytic methods that use Mn(III)–Cl intermediates have been developed for the same purpose. Solutions of Mn(III)Cl3 are meta stable, but they can be treated with ligands to prepare isolable Mn(III)Cl3 complexes, some of which are chemically useful as starting materials, such as [MnCl3(OPPh3)2].

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rdf:langString Manganese trichloride

rdf:langString trichloridobis(triphenylphopshineoxide)manganese(III)